|  Diamond is one of the two best known forms (or allotropes) of carbon, whose hardness and high dispersion of light makes it useful for industrial applications and jewelry. The other equally well known allotrope is graphite; but diamonds are specifically renowned as a mineral with superlative physical qualities. They make excellent abrasives because they can only be scratched by other diamonds, which also means they hold a polish extremely well and retain luster. About 130 million carats (26,000 kg) are mined annually, with a total value of nearly 9 billion US$.
The name "diamond" derives from the ancient Greek adamas (αδάμας; "impossible to tame"). They have been treasured as gems since their use as religious icons in India at least 2,500 years ago—and usage in drill bits and engraving tools also dates to early human history. Popularity of diamonds has risen since the 19th century because of improved cutting and polishing techniques, and they are commonly judged by the "four Cs": carat, clarity, color, and cut. Nearly four times the mass of natural diamonds are produced as synthetic diamond each year, though these are typically classified with poor-quality specimens that are suitable only for industrial-grade use.
Most natural diamonds originate from central and southern Africa, although significant sources of the mineral have been discovered in Canada, Russia, Brazil, and Australia. They are generally mined from volcanic pipes, which are deep in the Earth where the high pressure and temperature enables the formation of the crystals. The mining and distribution of natural diamonds are subjects of frequent controversy—such as with concerns over the sale of conflict diamonds by African paramilitary groups. There are also allegations that the De Beers Group misuses its dominance in the industry to control supply and manipulate price via monopolistic practices. Crystal structure Diamonds typically crystallize in the cubic crystal system and consist of tetrahedrally bonded carbon atoms. Lonsdaleite is a polymorph of diamond (and a distinct mineral species) that crystallizes with hexagonal symmetry; it is rarely found in nature, but is characteristic of synthetic diamonds. A cryptocrystalline variety of diamond is called carbonado. A colorless, grey or black diamond with a tiny radial structure is a spherulite.
The tetrahedral arrangement of atoms in a diamond crystal is the source of many of diamond's properties; graphite, another allotrope of carbon, has a rhombohedral crystal structure and as a result shows dramatically different physical characteristics—contrary to diamond, graphite is a very soft, dark grey, opaque mineral. Hardness Diamond is the hardest known naturally occurring material, scoring 10 on the relative Mohs scale of mineral hardness and having an absolute hardness value of between 167 and 231 gigapascals in various tests. Diamond's hardness has been known since antiquity, and is the source of its name. However, aggregated diamond nanorods, an allotrope of carbon first synthesized in 2005, are now believed to be even harder than diamond. Industrial use of diamonds has historically been associated with their hardness; this property makes diamond the ideal material for cutting and grinding tools. It is one of the most known and most useful of more than 3,000 known minerals. As the hardest known naturally occurring material, diamond can be used to polish, cut, or wear away any material, including other diamonds. Common industrial adaptations of this ability include diamond-tipped drill bits and saws, or use of diamond powder as an abrasive. Other specialized applications also exist or are being developed, including use as semiconductors: some blue diamonds are natural semiconductors, in contrast to most other diamonds, which are excellent electrical insulators. Industrial-grade diamonds are either unsuitable for use as gems or synthetically produced, which lowers their price and makes their use economically feasible. Industrial applications, especially as drill bits and engraving tools, also date to ancient times.
The hardness of diamonds also contributes to its suitability as a gemstone. Because it can only be scratched by other diamonds, it maintains its polish extremely well, keeping its luster over long periods of time. Unlike many other gems, it is well-suited to daily wear because of its resistance to scratching—perhaps contributing to its popularity as the preferred gem in an engagement ring or wedding ring, which are often worn everyday.
Toughness Unlike hardness, which only denotes resistance to scratching, diamond's toughness is only fair to good. Toughness relates to a material's ability to resist breakage from forceful impact. As with any material, the macroscopic geometry of a diamond contributes to its resistance to breakage. Diamonds cut into certain particular shapes are therefore more prone to breakage than others.
Color Diamonds occur in a variety of transparent hues — colorless, white, steel, blue, yellow, orange, red, green, pink, brown—or colored black. Diamonds with a detectable hue to them are known as colored diamonds. Colored diamonds contain impurities or structural defects that cause the coloration, while pure or nearly pure diamonds are transparent and colorless. Most diamond impurities replace a carbon atom in the crystal lattice. The most common impurity, nitrogen, causes a yellowish or brownish tinge.
Thermodynamic stability At surface air pressure (one atmosphere), diamonds are not as stable as graphite, and so the decay of diamond is thermodynamically favorable (ΔG = −2.99 kJ / mol). Diamonds will burn at approximately 800 degrees Celsius, providing that enough oxygen is available. This was shown in the late 18th century, and previously described during Roman times. So, despite the popular advertising slogan, diamonds are not forever. However, owing to a very large kinetic energy barrier, diamonds are metastable; under normal conditions, it would take an extremely long time (possibly more than the age of the Universe) for diamond to decay into graphite. Electromagnetic properties  Optical properties Diamonds exhibit a high dispersion of visible light. This strong ability to split white light into its component colors is an important aspect of diamond's attraction as a gemstone, giving it impressive prismatic action that results in so-called fire in a well-cut stone. The luster of a diamond, a characterization of how light interacts with the surface of a crystal, is brilliant and is described as adamantine, which simply means diamond-like. This is owed to their high refractive index of 2.417 (at 589.3 nm), which causes total internal reflection to occur. Some diamonds exhibit fluorescence of various colors under long wave ultraviolet light, but generally show bluish-white, yellowish or greenish fluorescence under X-rays. Some diamonds show no fluorescence.
This article is licensed under the GNU Free Documentation License. It uses material from the Wikipedia article Diamonds. |
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