Jewelry: Sapphire

Sapphire

Sapphire (from Hebrew: ספּיר Sapir) is the single-crystal form of aluminium oxide (Al2O3), a mineral known as corundum. It can be found naturally as gemstones or manufactured in large crystal boules for varied applications, including infrared optical components, watch faces, high-durability windows, and wafers for the deposition of semiconductors such as GaN nanorods.

The corundum group consists of pure aluminium oxide. Trace amounts of other elements such as iron, titanium and chromium give sapphires their blue, yellow, pink, purple, orange or greenish color. Sapphire includes any gemstone quality varieties of the mineral corundum except the fully saturated red variety, which is instead known as ruby.

Natural sapphire

Although blue is considered the normal color for sapphire, it is found in the full range of spectral colors as well as brown, colorless, grey and black. Any sapphire other than blue or fully saturated red (ruby) is considered a fancy color sapphire.

Blue sapphire

Various shades of blue result from titanium and iron inclusions within the aluminium oxide crystal lattice. Some stones are not well saturated and show tones of gray. It is common to bake natural sapphires to improve color. This is usually done by heating the sapphires to temperatures of up to 1800°C for several hours, or by heating in a nitrogen deficient atmosphere oven for 7 days or more. On magnification the silk due to included rutile needles are visible. If the needles are unbroken, then the stone was not heated. If the silk is not visible then the stone was heated adequately. If the silk is partially broken then a process known as low tube heat was used. Low tube heat is the process where the rough stone is heated to 1300 °C for 20 to 30 minutes over charcoal. This takes out any gray or brown in the stone and improves color saturation.

Fancy color sapphire

Purple sapphires are lower in price than blue ones. These stones contain the trace element vanadium and come in a wide variety of shades. Yellow and green sapphires have traces of iron which gives them their color. Pink sapphires have a trace element of chromium and the deeper the color pink the higher the value as long as the color is going toward red of rubies.


Color change sapphire

Color shift sapphires are blue in outdoor light and purple in indoor light. Color changes may also be pink in daylight to greenish in fluorescent light. Some stones shift color well and others only partially, in that some stones go from blue to blue purple. White sapphires usually come out of the ground as light gray or brown and are then heated to make them clear. However in very rare circumstances they will be


Star sapphire

A star sapphire is a type of sapphire that exhibits a star-like phenomenon known as asterism. Star sapphires contain intersecting needle-like inclusions (often the mineral rutile) that cause the appearance of a six-rayed 'star'-shaped pattern when viewed with a single overhead light source. Twelve-ray stars are also found, but are less common.

A "star sapphire" ring with two diamonds on a silver band. The value of a star sapphire depends not only on the carat weight of the stone but also the body color, visibility, and intensity of the star.

Treatments

Some sapphires are heat-treated or otherwise enhanced to improve their appearance and color, though some people object to such practices and prefer natural untreated stones. Treated stones tend to be darker than untreated stones and the treatment process causes changes to the internal structure that are generally easily detected.


Mining

Sapphires are mined from alluvial deposits or from primary underground workings. Historically, most sapphires have been mined in Sri Lanka, Madagascar and Myanmar. Australia leads the world in sapphire production (as of 1987) specifically from basalt derived placer deposits in Queensland and New South Wales. Pakistan, Afghanistan, India, Tanzania and Kenya also produce sapphires. The US state of Montana has produced sapphires from the Yogo Gulch deposit near Helena. Gem grade sapphires and rubies are also found in and around Franklin, North Carolina, USA. Several mines are open to the public.

Synthetic sapphire

Synthetic sapphire crystals can be grown in cylindrical crystal ingots of large size, up to many inches in diameter. As well as gemstone applications there are many other uses:

The first ever laser produced was based on the ruby chromium impurity in sapphire. While this laser has few applications, the Ti-sapphire laser is popular due to the relatively rare ability to tune the laser wavelength in the red-to-near infrared region of the electromagnetic spectrum. It can also be easily mode locked. In these lasers, a synthetically produced sapphire crystal with chromium or titanium impurities is irradiated with intense light from a special lamp, or another laser, to create stimulated emission.

Pure sapphire ingots can be sliced into wafers and polished to form transparent crystal slices. Such slices are used as watch faces in high quality watches, as the material's exceptional hardness makes the face almost impossible to scratch. Since sapphire ranks a 9 on the Mohs Scale, owners of such watches should still be careful to avoid exposure to diamond jewelry, and should avoid striking their watches against artificial stone and simulated stone surfaces. Such surfaces often contain materials including silicon carbide, which, like diamond, are harder than sapphire and thus capable of causing scratches (Scheel 2003).


Historical and cultural references

According to Rebbenu Bachya, the word "Sapir" in the verse Exodus 28:20 means "Sapphire" and was the stone on the Ephod representing the tribe of Issachar. However, this is disputed as the sapphire of the Bible was likely lapis lazuli (Texas Natural Science Center, 2006).
Supernatural powers were attributed to gems in India. One way this was manifested was the interdependence between gems and planets. Ruby, associated with the Sun, was the Lord of Gems, for the Sun lorded over all the planets. Blue sapphire is associated with Saturn (Wojtilla, 1973), yellow sapphire with Jupiter.

• Sapphire is the birthstone associated with September.
• The 45th wedding anniversary is known as the sapphire anniversary.
  
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This article is licensed under the GNU Free Documentation License. It uses material from the Wikipedia article Sapphire.

The History of Jewelry: Sapphires

Sapphires in the United States

The production of gem-quality sapphires in the United States is not new or recent. In 1865, the first U.S. sapphires were found in the gravels of the Missouri River in Lewis and Clark County, Montana. This was followed by subsequent discoveries on Dry Cottonwood Creek in Deer Lodge County in 1889, on Rock Creek in Granite County in 1892, and in Yogo Gulch in Judith Basin County in 1895. Additionally, small amounts of sapphire are recovered from Quartz Gulch in Granite County, Pole Creek in Madison County, the Missouri River in Chouteau County, and Brown's Gulch in Silver Bow County. Furthermore, corundum crystals, from which star sapphires have been cut, are found in Beaverhead and Madison Counties. Also, in 1895, the first sapphires were produced from the Cowee Valley in Macon County, North Carolina. But until very recently, with the exception of Yogo Gulch material, the commercial gemstone industry has had limited interest in U.S. sapphires.

Montana.--Mining of Yogo Gulch sapphires began within a year of their discovery in 1895 and continued for 39 years. In 1923, the mine was damaged so badly by rain that it could not economically recover. Other attempts have been made to commercially mine the deposit, but to date, all of these attempts have ended in economic failure.

Yogo's are unique among the world's sapphires. They lack the color zoning so prevalent in other sapphires, their uniform "corn-flower blue" color is natural (not the result of heat-treating), and their clarity is uniformly high. These features rank them among the world's finest sapphires. Unfortunately, the rough is both small and flat, wafer-like in shape. The majority of the crystals or pieces of crystals recovered are too small to be cut, most are less than 1 carat and finds of over 2 carats are rare. Reportedly, the largest crystal was a 19 carat stone found in 1910 that was cut into an 8-carat stone. The size of the cut stones greatly restrict the market for Yogo's, they are beautiful, small, very expensive sapphires.

Currently, Yogo sapphires are produced from three sources: Rancor lnc., produces material from the original Yogo Gulch deposit; Vortex Mining produces from a recently discovered extension of the Yogo dike; and material is produced by individuals from privately owned lots in Sapphire Village. The first two producers market only cut stones and finished goods and the third is comprised essentially of hobbyists.

Historically, the amount of sapphires produced from the Missouri River and Rock Creek areas greatly exceeded that from Yogo Gulch. However, the value of the material produced from Yogo, reported to be in excess of $30 million, is significantly greater than that of the combined values of the other areas. This relationship is rapidly changing.

The combination of large volume commercial operations on the Missouri River, and to some extent Rock Creek, plus the advent of successful heat-treating techniques for the material has greatly enhanced the acceptance of these sapphires by the gemstone industry. This enhanced acceptance has resulted in a significant increase in the market for and value of U.S. sapphires. Unconfirmed reports have circulated that a parcel of select 3- to 10-carat material, suitable for heat-treating, was sold for as much as $40,000 per kilogram. A more realistic price for 3- to 10-carat, sorted mine-run material is in the range of $5,000 per kilogram, with many kilograms of mine-run rough selling for $1,000 per kilogram.

The sapphires from the Missouri River gravels in Lewis and Clark County are a mixture of rough and pitted crystals showing well defined faces and completely rounded and smooth-surface highly stream worn pebbles. The majority of the material is pale blue or blue-green, with deep blue stones quite rare. Stones also are found in pastel blue, green, pink, pale red, purple, yellow, and orange. Most of the stones recovered are less than 6.4 millimeters in diameter, but material 6.4 to 12.7 millimeters in diameter are not uncommon. Material greater than 12.7 millimeters in diameter is rare.

Currently there are seven operations on the Missouri River that commercially produce sapphires and/or operate a dig-for-fee area. Not all of these may be active in any one year. It is the author's understanding that one operation, currently inactive, (a self-propelled floating 16-inch suction dredge) is for sale. The mines operate from about the last week of May through the first week of September.

The Rock Creek sapphires are very similar to the sapphires from the Missouri River but differ in the general shape of the crystals. The stones are basically crude hexagonal plates about the same dimension in width and height, with a much higher percentage of the material being well rounded water worn pebbles. There appears to be more of the larger sized (greater than 12.7 millimeters) material. Additionally, it is reported that the Rock Creek material has a greater percentage of stones that can be heat-treated for color enhancement.

During the past several years, there has been only a single producer on Rock Creek. The producer operated both a commercial recovery plant and a fee recovery area. The fee recovery area sold buckets of gravel for washing and also offered, for a predetermined fixed fee, the output of one day's operation of the commercial wash plant. There is work underway which would result in a second, much larger producer, opening an operation on another deposit in the area. If things go as planned, the new operation on Rock Creek would be the largest sapphire producer in Montana.

There are a number of locations between Dillon in Beaverhead County and Ennis in Madison County that produce lavender, grayish-lavender, bluish-gray, and gray hexagonal sapphire crystals that, when cut, produce stones that contain four- or six-ray stars. At least one producer from the Dillon area is currently advertising the availability of this type of material. The remainder of the sapphire deposits in Montana appear to be operated by individual hobbyists.

More should be said about the effects of heat-treating techniques on Montana sapphires, and the variety of fancy colored sapphires available. Not all Montana sapphires are suitable for heat- treating because of variations in chemical composition. Also, the sapphires from the Missouri River respond to heat-treating differently than those from Rock Creek The response to heat-treating can vary also depending upon the method (individual) used to treat the sapphires.

The yield on treatment of Missouri River sapphires is lower than for Rock Creek. It is reported that 20% to 30% of Missouri River sapphires heat-treat from deep, well saturated blue to pale, pale blue. The corresponding treatment rate for Rock Creek material is in the range of 60%. Heat-treating also yields or improves the color of fancy colored sapphires. Bright yellows and oranges are the result of heat-treating, whereas heat-treating improves the color of some pinks by removing colors that can interfere with the desirable pink shades. Montana sapphires can be diffusion treated, but because of their high iron content they are not particularly well suited for this form of enhancement.

North Carolina.--North Carolina is well known for its hobbyist production of sapphire. Sapphire have been produced from the Cowee Valley in Macon County since 1895 when the American Prospecting and Mining Co. systematically mined and washed the gravels of Cowee Creek. Today a number of dig-for-fee operations are located in the Cowee Valley. Each year many people pay to dig or purchase buckets of gravel to wash in hopes of finding a sapphire, garnets, and other gem materials. Many of the dig-for-fee operations have enriched the gravels with gem materials from other locations.

Every year articles appear in magazines and newspapers about large and valuable sapphires found at one or more of the mines in Cowee Valley. No doubt large corundum crystals and pieces of corundum are found each year. By the same token, valuable sapphires may be found, but the number of large valuable gemstones are far less than reported, and the values are generally not as great as reported. During the period when the area was commercially mined, gem material was found that would cut fine quality 3- to 4-carat stones, but the amount of quality gem material available has greatly declined. It is doubtful that North Carolina will ever again boast of commercial sapphire production, or that the commercial gemstone industry will seriously consider the State's sapphire deposits.